CAS号：

13115-71-4

分子式：

C7H15N3O5

分子量：

221.21100

中文名称：

甘氨酰-L-谷氨酰胺一水合物

英文名称：

中文别名：

甘氨酰-L-谷氨酰胺一水合物;甘氨酰-L-谷氨酰胺单水合物;甘氨酰-L-谷氨酰胺单水合物.甘氨酰-L-谷氨酰胺.甘氨酰谷氨酰胺.N-甘氨酰-L-谷氨酰胺.甘氨酰-L-谷氨;L-甘-谷二肽,甘氨酰-L-谷氨酰胺一水合物;L-甘-谷二肽;甘氨酰-L-谷氨酰胺;甘氨酰谷氨酰胺;甘氨酰-L-谷氨酰胺一水和物

英文别名：

Glycyl-L-glutamine monohydrate;
(S)-5-Amino-2-(2-aminoacetamido)-5-oxopentanoic acid;
H-Gly-Gln-OH;
Glycyl-L-glutamine;
(2S)-5-amino-2-[(2-aminoacetyl)amino]-5-oxopentanoic acid

精确分子量/精确质量：

221.10100

极性分子表面积/PSA：

144.74000

油水分配系数/LogP：

-0.49280
LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值，反映了物质在油水两相中的分配情况。其中、LogP值越大，说明该物质越亲油；反之，LogP值越小，则说明该物质越亲水。

InChI：

InChI=1/C7H13N3O4/c8-3-6(12)10-4(7(13)14)1-2-5(9)11/h4H,1-3,8H2,(H2,9,11)(H,10,12)(H,13,14)

外观与性状：白色晶体或结晶粉末

密度：1.359 g/cm3

熔点：194°C

沸点：643.1ºC at 760mmHg

闪点：342.7ºC

水溶解性：154 g/L (20 ºC)

折射率：-7 ° (C=3, 1mol/L HCl)

蒸汽压：3.4E-18mmHg at 25°C

其它信息：

1. 性状：未确定

2. 密度（g/mL,25℃）：未确定

3. 相对蒸汽密度（g/mL,空气=1）：未确定

4. 熔点（ºC）：194

5. 沸点（ºC,常压）：未确定

6. 沸点（ºC，0.1mmHg）：未确定

7. 折射率：未确定

8. 闪点（ºC）：未确定

9. 比旋光度（º，C=10，2N HCl）：-6.5

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（20ºC）：未确定

12. 饱和蒸气压（kPa,60ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：溶于水

制备方法

生化研究。

• 90641-30-8

  90641-30-8

• →

• 13115-71-4

  甘氨酰-L-谷氨酰胺一水合物

• 13139-62-3

  N2-chloroacetyl-glutamine

• →

• 13115-71-4

  甘氨酰-L-谷氨酰胺一水合物

• 888937-70-0

  888937-70-0

• →

• 13115-71-4

  甘氨酰-L-谷氨酰胺一水合物

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1、 摩尔折射率：46.72

2、 摩尔体积（m³/mol）：149.4

3、 等张比容（90.2K）：425.9

4、 表面张力（dyne/cm）：65.9

5、 极化率（10^-24cm³）：18.52

• 消光粉
• 流平剂
• 增稠剂
• 硅油
• 环氧树脂
• 光引发剂
• 丙烯酸树脂
• 紫外线吸收剂
• 钛白粉
• 增韧剂
• 增塑剂
• 醇胺类
• 三菱碳黑
• 抗静电剂
• 丙烯酸单体
• 附着力促进剂
• 抗氧剂
• 偶联剂
• 阻燃剂
• 醇醚类
• 纤维素酯
• 表面活性剂
• 水处理树脂
• 异氰酸酯固化剂
• 消泡剂
• 润湿剂
• 润滑剂
• 纤维素醚
• 有机颜料
• 蜡粉蜡乳液
• 多功能助剂
• 聚乙烯醇PVA
• 分散剂
• 高岭土
• 群青
• 氯醋树脂
• 无机颜料

1、 疏水参数计算参考值（XlogP）：-4.6

2、 氢键供体数量：4

3、 氢键受体数量：5

4、 可旋转化学键数量：6

5、 互变异构体数量：4

6、 拓扑分子极性表面积（TPSA）：136

7、 重原子数量：14

8、 表面电荷：0

9、 复杂度：241

10、 同位素原子数量：0

11、 确定原子立构中心数量： 1

12、 不确定原子立构中心数量：0

13、 确定化学键立构中心数量：0

14、 不确定化学键立构中心数量：0

15、 共价键单元数量：1

安全信息

海关代码：2924199090

WGK_Germany：-
德国有关水污染物质的分类清单

危险类别码：R36/37/38

安全说明：S23-S24/25-S37/39-S26

安全标志：S23:不要吸入蒸汽。
S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S24/25:防止皮肤和眼睛接触。
:

危险标志：Xi:Irritant;

海关信息

海关数据查看详细

中国海关编码：2924199090

概述：2924199090. 其他无环酰胺（包括无环氨基甲酸酯)(包括其衍生物及盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素：品名, 成分含量, 用途, 包装

摘要/Summary：2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Name:	Glycyl-L-glutamine monohydrate 99% Material Safety Data Sheet
Synonym:	Glutamine (L)-, glycyl
CAS:	13115-71-4

Section 1 - Chemical Product   MSDS Name:Glycyl-L-glutamine monohydrate 99% Material Safety Data Sheet

Synonym:Glutamine (L)-, glycyl

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
13115-71-4	Glycyl-L-glutamine monohydrate	99	unlisted

Hazard Symbols: None Listed.

Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION

  EMERGENCY OVERVIEW

The toxicological properties of this material have not been fully investigated.

Potential Health Effects

Eye:

May cause eye irritation.

Skin:

May cause skin irritation.

Ingestion:

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.

Inhalation:

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.

Chronic:

No information found.

Section 4 - FIRST AID MEASURES

  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Skin:

Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Ingestion:

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation:

Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES

  General Information:

As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.

Extinguishing Media:

Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES

  General Information: Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:

Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE

  Handling:

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Storage:

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION

  Engineering Controls:

Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.

Exposure Limits CAS# 13115-71-4: Personal 手感助剂ive Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin:

Wear appropriate protective gloves to prevent skin exposure.

Clothing:

Wear appropriate protective clothing to prevent skin exposure.

Respirators:

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

 

Physical State: Solid

Color: white

Odor: none reported

pH: Not available.

Vapor Pressure: Not available.

Viscosity: Not available.

Boiling Point: Not available.

Freezing/Melting Point: > 194 deg C

Autoignition Temperature: Not applicable.

Flash Point: Not applicable.

Explosion Limits, lower: Not available.

Explosion Limits, upper: Not available.

Decomposition Temperature: >160 deg C

Solubility in water: 154 g/l (20 c)

Specific Gravity/Density: Not available.

Molecular Formula: C7H13N3O4.H2O

Molecular Weight: 221.22

Section 10 - STABILITY AND REACTIVITY

  Chemical Stability:

Stable under normal temperatures and pressures.

Conditions to Avoid:

Incompatible materials, strong oxidants.

Incompatibilities with Other Materials:

Oxidizing agents.

Hazardous Decomposition Products:

Irritating and toxic fumes and gases.

Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION

  RTECS#:

CAS# 13115-71-4 unlisted.

LD50/LC50:

Not available.

Carcinogenicity:

Glycyl-L-glutamine monohydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

 

Section 13 - DISPOSAL CONSIDERATIONS

  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

 

IATA

Not regulated as a hazardous material.

IMO

Not regulated as a hazardous material.

RID/ADR

Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

 

European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols: Not available.

Risk Phrases:

Safety Phrases:

S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/手感助剂ion)

CAS# 13115-71-4: 0

Canada

None of the chemicals in this product are listed on the DSL/NDSL list.

CAS# 13115-71-4 is not listed on Canada's Ingredient Disclosure List.

US FEDERAL

TSCA

CAS# 13115-71-4 is not listed on the TSCA inventory.

It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION

N/A